Affordable Access

Publisher Website

Synthesis and some properties of charge transfer complexes of C60with asymmetric donors of tetrathiafulvalene family

Authors
Journal
Journal of Physics and Chemistry of Solids
0022-3697
Publisher
Elsevier
Publication Date
Volume
58
Issue
11
Identifiers
DOI: 10.1016/s0022-3697(97)00089-9
Keywords
  • Fullerene C60
  • Asymmetric Tetrathiafulvalenes
  • Tg-Analysis
  • Ir-
  • X-Ray Photoelectron Spectroscopy
  • Charge Transfer Complexes

Abstract

Abstract New charge transfer complexes: (TMDTDM-TTF) 2C 60(CS 2) 3, TMDTDM-TTF · C 60 · C 6H 6, (EDTTTF) 2C 60CS 2 were synthesized by the reaction of C 60 with asymmetric donors in CS 2 and benzene. XPS- and IR-spectroscopy show a weak charge transfer in these compounds. The influence of the solvents during the formation of the complexes was disscussed. The (TMDTDM-TTF) 2C 60(CS 2) 3 crystal structure reveals that it has a layered structure with alternating sheets of C 60 and donor dimers.

There are no comments yet on this publication. Be the first to share your thoughts.