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Dichlorido(2,3-di-2-pyridyl­pyrazine-κ2 N 1,N 2)palladium(II)

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
11
Identifiers
DOI: 10.1107/s1600536811044369
Keywords
  • Metal-Organic Papers

Abstract

The PdII ion in the title complex, [PdCl2(C14H10N4)], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 14.4 (3)°], whereas the uncoordinated pyridine ring is inclined considerably to the pyrazine ring [dihedral angle = 52.2 (2)°]. The dihedral angle between the two pyridine rings is 58.8 (2)°. In the crystal, complex mol­ecules are connected by inter­molecular C—H⋯Cl and C—H⋯N hydrogen bonds, forming a three-dimensional network. Intra­molecular C—H⋯Cl hydrogen bonds are also present.

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