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Stabilization in the order I>Br>Cl among trimethylsilylmethyl halides, compared to carbon analogs. Possible role of electronegativity in organosilicon chemistry

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
22
Issue
14
Identifiers
DOI: 10.1016/s0040-4039(01)90300-4

Abstract

Abstract Electronegativities may be used to rationalize the observation that the equilibrium, CH 3(CH 2) 3I + (CH 3) 3SiCH 2Cl ⇌ CH 3(CH 2) 3Cl + (CH 3) 3SiCH 2I, lies to the right.

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