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Some phosphine oxide and sulphoxide complexes of Nb(V), Mo(V) and W(VI) oxochlorides

Authors
Journal
Journal of the Less Common Metals
0022-5088
Publisher
Elsevier
Publication Date
Volume
57
Issue
1
Identifiers
DOI: 10.1016/0022-5088(78)90166-2
Disciplines
  • Physics

Abstract

Abstract The new complexes MoOCl 3 · 2Ph 2SO and WOCl 4 · Ph 3PO have been prepared by the reaction of MoCl 5 and WOCl 4 with the appropriate ligand. These complexes have been characterised by analysis, infrared and Raman spectra, X-ray powder diffraction and measurements of melting point, electrical conductivity and molecular weight. Some physical properties of NbOCl 3 · 2L (where L = Ph 2SO, Ph 3PO and (Me 2N) 3PO) are reported.

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