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Chemoselective deprotection of tertiary benzylamines and reduction of carbon–carbon double bonds in the presence of benzyl and benzyloxymethyl ethers

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
41
Issue
32
Identifiers
DOI: 10.1016/s0040-4039(00)01013-3
Keywords
  • Chemoselective
  • Deprotection
  • Benzylamines
  • Reduction
  • Olefins

Abstract

Abstract Catalytic transfer hydrogenation using 10% Pd–C in the presence of 1,4-cyclohexadiene as the hydrogen donor selectively debenzylates amines and reduces carbon–carbon double bonds while leaving benzyl and benzyloxymethyl ethers intact.

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