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The reaction of triethylamine with bromine. An evaluation of the formation constant of the transient 1:1 complex and a study of its conversion into products.

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
23
Issue
35
Identifiers
DOI: 10.1016/s0040-4039(00)87692-3

Abstract

Abstract Triethylamine and bromine in 1,2-dichloroethane give a non isolable 1:1 charge transfer complex with K f>10 7 M −1, which undergoes a fast intramolecular oxidation to N,N-diethylethyldeneiminium bromide and hydrogen bromide.

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