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Hydroxypinanone: Solute/solute interactions and non-linear chiroptical properties

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
38
Issue
33
Identifiers
DOI: 10.1016/s0040-4039(97)01301-4

Abstract

Abstract The non-linear behaviour of the optical rotation in CHCl 3 and EtOH of a rigid hydroxyketone often used as chiral auxiliary in enantioselective syntheses is described. It is also shown that ethanol in spite of its ability to disrupt solute/solute interactions through H-bond formation leads also to significant discrepencies.

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