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Cyclization versus polymerization in polycondensation reactions under continuous addition of two symmetrical monomers.

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
28
Issue
4
Identifiers
DOI: 10.1016/s0040-4039(00)95744-7
Disciplines
  • Chemistry

Abstract

Abstract The yields of cyclic oligomers formed in the reactions of two symmetrical monomers are calculated as a function of the dilution and the rate constants of the chemical steps. The consequences for the synthetic strategy for large cycles and the information on the conformation of linear oligomers from yields are discussed.

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