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Electrochemical study of titanium in chloride-fluoride melts

Authors
Journal
Electrochimica Acta
0013-4686
Publisher
Elsevier
Publication Date
Volume
31
Issue
2
Identifiers
DOI: 10.1016/0013-4686(86)87102-x
Disciplines
  • Chemistry

Abstract

Abstract The study of electrochemical reduction of titanium in molten NaClKClK 2TiF 6 by means of linear sweep voltammetry and the quasi-steady-state method has revealed that the reduction of Ti(IV) to Ti proceeds reversibly in two consequent steps The temperature dependence of the equilibrium constant for the metal—salt interaction is established. The effect of the fluorine ion concentration on the interaction mechanism of Ti metal with chloride—fluoride melts containing tetravalent ions of titanium is considered.

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