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Synthesis and derivatisation ofN,N′-trisubstituted 1,2-diamines derived from (1R,2R)-1,2-diaminocyclohexane

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
46
Issue
20
Identifiers
DOI: 10.1016/j.tetlet.2005.03.129

Abstract

Abstract The synthesis of N, N′-trisubstituted 1,2-diamines can be achieved by simple reduction of an aminal derived from (1 R,2 R)-diaminocyclohexane. We comment on the scope and limitation of this reduction and discuss its application towards the synthesis of unsymmetrical N, N′-tetrasubstituted 1,2-diamines.

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