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Asymmetric hydrocarboxylation of olefins:IV. Influence of PPh 3 in the asymmetric hydrocarboxylation catalyzed by [(—)-DIOP]PdCl 2

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
132
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)93732-x

Abstract

Abstract In the palladium-catalyzed hydrocarboxylation of α-methylstyrene using PPh 3 and (—)-DIOP as ligands, with a constant ratio of phosphorus to palladium atoms of 2, the optical yield depends on the proportions of PPh 3 and (—)-DIOP, showing a maximum for a molar ratio of 2.

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