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High resolution FTIR spectra of theν9vibrational band ofcis-rotamers HCOOH and H13COOH

Authors
Journal
Journal of Molecular Structure
0022-2860
Publisher
Elsevier
Publication Date
Volume
795
Identifiers
DOI: 10.1016/j.molstruc.2006.02.023
Keywords
  • Formic Acid
  • Cis-Rotamer
  • Ftir Spectroscopy

Abstract

Abstract High resolution FTIR spectra of the ν 9 vibrational band of cis-rotamers for both parent and 13C isotopically substituted formic acid molecules have been observed and analyzed. Rotational and centrifugal distortion parameters of the 9 1 vibrational states have been obtained or improved. The band centers for cis-HCOOH and cis-H 13COOH have been determined to be 493.4205092(73) and 492.938656(19) cm −1, respectively.

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