Affordable Access

Publisher Website

Assignment of overtone and combination bands in the vibrational spectrum of CD3I

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
28
Issue
8
Identifiers
DOI: 10.1016/0584-8539(72)80135-1

Abstract

Abstract A number of overtone and combination banda in the i.r. spectrum of CD 3I have been measured at medium or high resolution and the rotational fine structure of these bands has been analyzed to obtain estimates of the rotational constants of the excited vibrational states. From these results we are able to estimate the values of the rotational constants A 1, A 2, A 4 and B 4. The new measurements confirm many previous assignments of the overtone and combination bands with some revisions and also reveal five bands not previously reported. Further, the analysis of the rotational structure yields precise estimates of the vibrational origins of the overtone and combination bands and these values have been used to estimate the anharmonic constants x ss' and gtt' for CD 3I.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments

More articles like this

Intensities of binary overtone and combination ban...

on Spectrochimica Acta Part A Mol... Jan 01, 1977

Assignment of the overtones and combination bands...

on Spectrochimica Acta Part A Mol... Jan 01, 1996

Study of overtones and combination bands in the in...

on Chemical Physics Letters Jan 01, 1989
More articles like this..