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On the fate of the Ti catalyst during hydrogen cycling of sodium alanate

Authors
Journal
Journal of Alloys and Compounds
0925-8388
Publisher
Elsevier
Publication Date
Volume
393
Identifiers
DOI: 10.1016/j.jallcom.2004.09.061
Keywords
  • Hydrogen Storage
  • Alanate
  • Metal Hydrides
  • X-Ray Diffraction

Abstract

Abstract The state of the titanium catalyst species formed upon doping and hydrogen cycling of NaAlH 4 with Ti-catalysts was studied by X-ray diffraction analysis. After doping with TiCl 3, Ti is present as an hcp-Ti(Al) solid solution, while for the Ti(OBu) 4 doped system, Ti exists as an XRD-amorphous phase. Cycling of hydrogen for 1.5 times results in transformation of these initially different Ti compounds into similar compounds, whose composition is dependent on the temperature. Thus, if low temperatures were used during the cycling process (up to 175 °C) an amorphous Al–Ti alloy formed, while upon using high temperatures (200 °C and higher) Ti was present as an Al x Ti intermetallic. Correlation of the XRD and hydrogen desorption curves shows that the most active catalyst species in the present system is the amorphous Al–Ti alloy, whereas a decreased catalytic activity is found for the Al x Ti intermetallic.

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