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A formal total synthesis of (±)-pseudomonic acid A

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
36
Issue
42
Identifiers
DOI: 10.1016/0040-4039(95)01590-e

Abstract

Abstract The pyran nucleus pseudomonic acid A has been prepared via a furan oxidation strategy. Introduction of the C-8 sidechain (pseudomonic acid numbering) was accomplished regio- and stereoselectively by either the Johnson variation of the Claisen rearrangement or by Pd-catalyzed allylic displacement.

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