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Reactivity of hydroxo, hydroperoxo and peroxo platinum(II) derivatives towards carbon oxides

Authors
Journal
Inorganica Chimica Acta
0020-1693
Publisher
Elsevier
Publication Date
Volume
173
Issue
2
Identifiers
DOI: 10.1016/s0020-1693(00)80218-2

Abstract

Abstract The reaction of the complexes Pt(PPh 3) 2(OOH)X (HX=succinimide ( I), phthalimide ( II), PhOH ( III), ϱ-MeC 6H 4OH ( IV)) and Pt(PPh 3) 2(OH)X (HX= succinimide ( V), phthalimide ( VI)) with CO and CO 2 have been studied. In order to clarify some reaction pathways, the reactivity of Pt[O 2C(O)O ](PPh 3) 2 ( VII) and of Pt[O 2CMe 2O ](PPh 3) 2 ( VIII) with succinimide and phthalimide has also been investigated. 17O NMR and IR spectra of some of these compounds and of Pt[OC(O)O ](PPh 3) 2 ( IX) have been recorded.

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