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The reaction of ammonium pollysulphide with benzylidene chloride and some derivatives thereof

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
22
Issue
2
Identifiers
DOI: 10.1016/0040-4020(66)80005-4

Abstract

Abstract The reaction of ammonium polysulphide with benzylidene chloride and certain of its chloro, methoxy and methyl derivatives has been investigated. Benzylidene chloride, p-chlorobenzylidene chloride p-methoxybenzylidene chloride and p-methylbenzylidene chloride gave the corresponding thiobenzamides. o-Chlorobenzylidene chloride afforded bis- o-chlorobenzyl disulphide and under different conditions a polymer. 2,6-Dichlorobenzylidene chloride gave bis-2,6-dichlorobenzyl trisulphide.

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