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Stereocontrolled synthesis of 7-hydroxy- and 7-acetoxy-PGI2: New stable PGI2analogues

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
22
Issue
15
Identifiers
DOI: 10.1016/s0040-4039(01)90337-5

Abstract

Abstract Stable analogues of PGI 2, 7-hydroxy- and 7-acetoxy-PGI 2, were synthesized from protected PGI 2 methyl ester 1b via sulfoxides 6a , 6b through stereocontrolled sulfoxide-sulfenate rearrangement.

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