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Ligand basicities from reactions with Nd[(CF3CO)2CH]3·THF

Authors
Journal
Inorganica Chimica Acta
0020-1693
Publisher
Elsevier
Publication Date
Volume
147
Issue
1
Identifiers
DOI: 10.1016/s0020-1693(00)80642-8

Abstract

Abstract Proton NMR spectroscopy has been used to obtain the equilibrium constants for the reaction in CDCl 3 solvent: where B represents neutral bases with oxygen or nitrogen donors. The Δ G of reaction is well correlated with the Gutmann donor number of the bases. For the oxygen bases, Δ G correlates with Drago's E B parameter but not the C B parameter; for the nitrogen bases, the reverse was obtained ( i.e., correlation with the C B but not the E B).

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