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Stereochemical aspects of photo-set induced diradical cyclization reactions as part of isoquinoline alkaloid synthetic strategies

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
30
Issue
7
Identifiers
DOI: 10.1016/s0040-4039(01)80617-1

Abstract

Abstract Studies of the photo-SET induced cyclization reactions of an N-silylbenzyldihydroisoquinolinium salt have uncovered a potentially interesting feature governing stereoselectivities of diradical cyclization reactions.

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