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Synthesis of a novel bidentate complex of η5-C5H4CH2CH(CH3N(CH 3)(C 3H 5)Mn(CO)2

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
403
Issue
3
Identifiers
DOI: 10.1016/0022-328x(91)86482-6

Abstract

Abstract Irradiation of the half-sandwich manganese tricarbonyl complex η 5-C 5H 4CH 2CH(CH 3)NH(CH 3)Mn(CO) 3m, which itself contained a secondary amine branch on the cyclopendatidenyl group, to give bidentate complex, η 5-C 5H 4CH 2(CH 3) NHCH 3M n(CO) 2. Deprotonation followed by allylation gave N-allylation compound, η 5-C 5H 4CH 2CH(CH 3) N(CH 3)(C 3H 5)M n(CO) 2, which was unequivocally identified by spectroscopic and X-ray diffraction studies.

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