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Reactions of Dicyclopentadienyltitanium(III) compounds with carbon monoxide

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
181
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)85737-x

Abstract

Abstract Reactions of Cp 2TiR (R = Cl, C 6F 5, C 6H 5, o-CH 3C 6H 4) with CO give two types of products: terminally coordinated adducts, Cp 2Ti(R)CO, and insertion products, Cp 2TiCOR, i.e. acyl compounds. The acyl ligand is η 2-coordinated at the titanium atom. The preparations and properties of the compounds are described.

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