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Ligand free copper-catalyzed heterogeneous O-arylation reaction under green condition

Authors
Journal
Catalysis Communications
1566-7367
Publisher
Elsevier
Identifiers
DOI: 10.1016/j.catcom.2014.09.006
Keywords
  • Post-Synthetic Modification
  • Irmof-3
  • Cu(Ii)
  • Heterogeneous Catalysis
  • O-Arylation
  • Shape Selectivity

Abstract

Abstract A highly porous Zn-based iso-reticular metal–organic framework (IRMOF-3) has been selected for covalent modification. Pyridine-2-aldehyde has been used to decorate the free amine group of IRMOF-3 in the porous matrix. Schiff base moiety thus generated has been availed to anchor copper(II) ions to prepare the desired catalyst that catalyzes O-arylation reactions heterogeneously under mild reaction conditions. Porous catalyst demonstrates size selectivity in products when various substrates undergo O-arylation with α and β-naphthol.

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