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Magnetic properties of TiLnS2compounds (Ln  Nd, Gd, Dy, Er and Yb)

Authors
Journal
Journal of Alloys and Compounds
0925-8388
Publisher
Elsevier
Publication Date
Volume
209
Identifiers
DOI: 10.1016/0925-8388(94)91112-6

Abstract

Abstract Magnetic properties of the thallium lanthanide disulphides (TlLnS 2, Ln  Nd, Gd, Dy, Er and Yb) were investigated. They crystallize with the rhombohedral structure ( R 3 m , α-NaFeO 2 type). Parameters of the crystal field Hamiltonian were deduced from the high field magnetization assuming trigonally distorted octahedral symmetry of the coordination spheres of metal ions. The second-order crystal field parameter was correlated with the deformation of LnS 6 octahedra.

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