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Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 2: Derivatization

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
63
Issue
18
Identifiers
DOI: 10.1016/j.tet.2007.02.076
Keywords
  • Chlorin
  • Deuteration
  • Bromination
  • Metalation

Abstract

Abstract Stable chlorins bearing few or no substituents have been subjected to a variety of reactions including demetalation, magnesium insertion, oxochlorin formation, and bromination followed by Suzuki coupling. The kinetics of deuteration also have been determined for two oxochlorins and a series of chlorins bearing 0, 1, 2, or 3 meso-aryl substituents.

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