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The inhibition of Cd(II) reduction at the DME from aqueous 1 M NaClO4by sucrose

Authors
Journal
Journal of Electroanalytical Chemistry
0022-0728
Publisher
Elsevier
Publication Date
Volume
282
Identifiers
DOI: 10.1016/0022-0728(91)85095-7

Abstract

Abstract It is shown that the steps in the earlier established CEE mechanism for the charge transfer process of Cd(II) reduction all are slowed down upon addition of sucrose. An attempt is made to correlate the individual standard rate constants with (i) the surface coverage by sucrose, and (ii) the viscosity of the solution layer adjacent to the electrode surface. No clear relationships are obtained, thus leaving the physical nature of the effects unexplained.

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