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Construction of NiCo–Pt nanopolyhedron inlay-structures and their highly efficient catalysis hydrolytic dehydrogenation toward ammonia borane

Authors
Journal
Journal of Power Sources
0378-7753
Publisher
Elsevier
Publication Date
Volume
232
Identifiers
DOI: 10.1016/j.jpowsour.2012.12.070
Keywords
  • Nico–Pt Nanopolyhedrons
  • Inlay-Structures
  • Catalysis
  • Dehydrogenation
  • Ammonia Borane
Disciplines
  • Chemistry
  • Design

Abstract

Graphical abstract New designed NiCo–Pt nanopolyhedrons inlay-structures, synthesized by galvanic replacement method, exhibit exceedingly high catalytic activity to dehydrogenation toward boron hydride under moderate conditions due to the cooperation of high proportional active crystal surface and inlay-heterostructures. This excellent function empowers the potential of the product for its possible application on energy source and chemical industry. Highlights ► New designed NiCo–Pt nanopolyhedron inlay-structures have been firstly reported in this work. ► NiCo–Pt hexagonal-nanoplates exhibit exceedingly high dehydrogenation catalytic activity. ► NiCo–Pt magnetic nanopolyhedrons can be separated and recovered for recyclable use. ► As-obtained NiCo–Pt nanopolyhedrons have the potential application in energy source.

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