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Enantioselection in the birch reduction-alkylation of a chiral benzoic acid derivative

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
25
Issue
41
Identifiers
DOI: 10.1016/s0040-4039(01)91207-9

Abstract

Abstract Preparation and diastereoselective Birch reduction-alkylation of benzoxazepenone 3 is described; conversion of 3 to ≈ enantiomerically pure 11 confirms the ∼98:2 diastereoselection in the alkylation step.

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