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UV and NMR studies of alkyl-substituted germyl anions

Authors
Journal
Polyhedron
0277-5387
Publisher
Elsevier
Publication Date
Volume
9
Issue
18
Identifiers
DOI: 10.1016/s0277-5387(00)86952-1

Abstract

Abstract Several (trialkylgermyl)alkali metals (M = Li, Na, K) were investigated by UV, 1H and 13C NMR spectroscopic methods to clarify the nature of a germanium-(alkali metal) bond. On conversion of a trialkylgermane to the corresponding germylalkali metals, the bathochromic shift of UV absorption maxima, upfield shift of the 1H NMR signals and downfield shift of the 13C NMR signal are observed.

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