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A rare pentanuclear CuII-based coordination framework exhibiting coexistence of antiferromagnetic and ferromagnetic couplings

Authors
Journal
Inorganic Chemistry Communications
1387-7003
Publisher
Elsevier
Volume
35
Identifiers
DOI: 10.1016/j.inoche.2013.05.020
Keywords
  • Pentacopper(Ii) Cluster
  • Hydrothermal Reaction
  • Pcunet
  • Antiferromagnetic And Ferromagnetic Couplings
Disciplines
  • Earth Science
  • Geography
  • Physics

Abstract

Abstract A unique pentacopper(II) cluster-based 3-D coordination framework, [Cu5(nip)4(μ3-OH)2-(dps)2(H2O)4]n, has been prepared by hydrothermal reaction of Cu(II) with 5-nitroisophthalic acid (H2nip) and 4,4′-dipyridylsulfide ligands (dps), which exhibits a 6-connected pcu net and coexistence of antiferromagnetic and ferromagnetic couplings.

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