Affordable Access

Publisher Website

High-pressure study of the intramolecular electron-transfer luminescence of 9,9′-bianthryl in viscous solvents

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
107
Issue
2
Identifiers
DOI: 10.1016/0009-2614(84)85695-x

Abstract

Abstract The intramolecular electron-transfer state of 9,9′-bianthryl was investigated in viscous solvents at high pressures. In the low-pressure region, there is a true equilibrium between the electron transfer and locally excited states, whereas the increase in the viscosity of the solvents becomes the dominant factor in the high-pressure region. In particular, a change in the kinetics was observed in i-butanol and in i-amyl alcohol as the pressure was increased to 10 kbar.

There are no comments yet on this publication. Be the first to share your thoughts.