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Zero-field splittings of phenanthroline-localized3ππ* emitting levels in mixed-ligand zinc(II) complexes

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
174
Issue
2
Identifiers
DOI: 10.1016/0009-2614(90)80102-j

Abstract

Abstract Zero-field splittings of the phenanthroline-localized 3ππ* state in series of mixed-ligand zinc(II) complexes, Zn(X-PhS) 2(phen) (X = F 5, 4-Cl, 4-CH 3) were observed. The results are interpreted in terms of mixing with the nearby lowest ligand—ligand charge-transfer excited triplet level. By employing reasonable assumptions the mixing coefficients were determined.

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