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An unusual 3D complex showing 5,8-connected topology with encapsulated 8-connected octamolybdate polyoxoanions

Authors
Journal
Inorganic Chemistry Communications
1387-7003
Publisher
Elsevier
Publication Date
Volume
12
Issue
9
Identifiers
DOI: 10.1016/j.inoche.2009.07.001
Keywords
  • Polyoxometalate
  • Organic–Inorganic Hybrid
  • Octamolybdate
  • Topochemistry
Disciplines
  • Mathematics

Abstract

Abstract An unprecedented inorganic–organic framework, containing octamolybdate polyoxoanions as 8-connected nodes, defines a new 5,8-connected topology and represents 8-fold interpenetrated srs ( SrS 2 ) topological Cu(I)-organic secondary network for the first time. While the free bipy ligand displays weak luminescence in the solid state at room temperature, this compound exhibits an intense yellow radiation emission maximum at λ ≈ 567 nm upon excitation at λ ≈ 365 nm.

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