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A new approach to the synthesis of a polyfunctional acyclic chiral building block based on ethyl (S)-(–)-lactate

Authors
Journal
Mendeleev Communications
0959-9436
Publisher
Elsevier
Publication Date
Volume
9
Issue
2
Identifiers
DOI: 10.1070/mc1999v009n02abeh000882

Abstract

Based on ethyl ( S)-(–)-lactate, an original sequence of highly stereoselective transformations leading to (4 S,5 E)-4-bromomethylhept-5-enenitrile was developed using rearrangement of a chiral cyclopropyl carbinol as the key step.

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