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Esterification of hemins with trimethyloxonium tetrafluoroborate

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Elsevier
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Abstract

A procedure has been developed for the methylation of hemins using trimethyloxonium tetrafluoroborate. The method is rapid and selective for carboxyl groups, and it can be used to methylate polar and nonpolar hemins under neutral and basic conditions. Esterifications of protohemin IX, hematohemin, and heme a have been accomplished in high yield.

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