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Radiation sensitive indicator based on tetrabromophenol blue dyed poly(vinyl alcohol)

Authors
Journal
Radiation Physics and Chemistry
0969-806X
Publisher
Elsevier
Volume
86
Identifiers
DOI: 10.1016/j.radphyschem.2013.01.019
Keywords
  • Tetrabromophenol Blue
  • Poly(Vinyl Alcohol)
  • Radiation Dosimetry
  • Thin Polymeric Films

Abstract

Abstract Radiation sensitive indicators based on dyed polyvinyl alcohol (PVA) containing acid- sensitive dye (tetrabromophenol blue, TBPB) and chloral hydrate (CCl3·CH·(OH)2, 2,2,2-trichloroethane-1,1-diol) have been developed. These plastic film dosimeters undergo color change from blue (the alkaline form of TBPB) to yellow (the acidic form of TBPB), indicating acid formation. The concentration of radiation formed acids in the films containing different concentrations of chloral hydrate was calculated at different doses. These films can be used as dosimeters for food irradiation applications where the maximum of the useful dose ranges are between 1 and 8kGy depending on chloral hydrate concentration in the film. The films have the advantage of negligible humidity effects on response in the intermediate range of relative humidity from 0 to 70% as good post irradiation stability when stored in the dark at room temperature. The overall combined uncertainty (at 2σ) associated with measurement of response (ΔAmm−1) at 623nm for dose range 1–8kGy is 4.53%.

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