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Matrix isolation studies of water complexes

Authors
Journal
Journal of Molecular Structure
0022-2860
Publisher
Elsevier
Publication Date
Volume
222
Identifiers
DOI: 10.1016/0022-2860(90)80010-h

Abstract

Abstract The reason why HDO prefers to form a deuterium bond instead of a hydrogen bond is discussed. The average structure of a complex may differ for different isotopomers if the intermolecular potential energy function has a flat minimum. This is illustrated for the water complexes of methylsubstituted benzenes. The intermolecular fundamentals of the water ammonia complex are discussed. A possible mechanism for secondary isotope shifts in intramolecular vibrations of complex forming molecules is given.

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