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Effect of ionic media on the stability constants of chloride, nitrate and thiocyanate complexes of americium(III) and europium(III)

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
33
Issue
2
Identifiers
DOI: 10.1016/0022-1902(71)80392-5

Abstract

Abstract Stability constants of Am(II) and Eu(III) complexes with chloride, nitrate and thiocyanate ions have been determined in lithium, hydrogen, sodium and ammonium ion media at 30±0·1°C and unit ionic strength, by a solvent extraction method. For chloride complexes, the first stability constant K 1 has been found to increase regularly with decreasing hydration of the medium cations. The effect of medium cations on the stabilities of nitrate and thiocyanate complexes has been found to be much smaller.

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