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Conformational studies on peptides—I:Circular dichroism of cyclo-γ-oligoglutamic acids

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
27
Issue
22
Identifiers
DOI: 10.1016/s0040-4020(01)91731-4
Disciplines
  • Philosophy

Abstract

Abstract CD properties of three cyclo-γ-oligoglutamic acids and their t-butyl esters are reported. The assignments of the different Cotton effects are discussed. The CD of the cyclodipeptide is interpreted on the basis of a conformation with two trans amide groups in anti positions. A phenomenological correlation between chiroptical properties and conformation is presented for the other cyclooligopeptides.

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