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Derivation and experimental verification of approximate explicit equations in differential pulse polarography:Part III. Diagnostic criteria for characterization of first-order processes

Authors
Journal
Journal of Electroanalytical Chemistry
0022-0728
Publisher
Elsevier
Publication Date
Volume
241
Identifiers
DOI: 10.1016/0022-0728(88)85132-5
Disciplines
  • Chemistry
  • Medicine

Abstract

Abstract From an approximate equation previously derived, several diagnostic criteria have been developed to differentiate electrochemical processes coupled or not to first-order reactions. To check these criteria, they have been applied to the reductions of Cd(II) ion, diacetyl and alloxan, and a close agreement between experimental and theoretical results was obtained in all cases. Moreover, the range of applicability of these equations is also discussed and tested.

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