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A facile synthesis of α-phosphono esters through methoxycarbonylation of α-phosphono carbanions

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
35
Issue
48
Identifiers
DOI: 10.1016/0040-4039(94)88430-7

Abstract

Abstract This paper describes a concise and effective synthesis of methyl α-phosphonoaryl acetates, effected by reacting α-phosphono carbanions with methyl chloroformate. Yields are high, and the purification of the products is readily achieved with column chromatography.

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