Affordable Access

Publisher Website

Reorientation in H-NH2collisions, a spin correlated interaction

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
86
Issue
2
Identifiers
DOI: 10.1016/0009-2614(82)83266-1

Abstract

Abstract We present polarised fluorescence data and a theoretical study of inelastic energy transfer in the NH 2-H system. Rotational transfer lines are weakly polarised, and branching ratios and polarisations depend on the spin component of the radical initially excited. Polarisation ratios are calculated using the distorted-wave Born approximation with a spin correlated potential operator. Spin-dependent terms are predicted to be more reorienting than the spin-independent part.

There are no comments yet on this publication. Be the first to share your thoughts.