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Stereochemical and mechanistic aspects of the nickel complex catalysed formation of olefins from allylic alcohols and Grignard reagents

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
22
Issue
12
Identifiers
DOI: 10.1016/s0040-4039(01)90263-1

Abstract

Abstract The reaction of (+)-S-but-1-en-3-ol with phenylmagnesium bromide in the presence of bis(triphenylphosphine)nickel dichloride has been shown to proceed with inversion of configuration to yield (−)-R-3-phenylbut-1-ene.

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