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CH-activation of methane – Synthesis of an intermediate?

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Identifiers
DOI: 10.1016/j.jorganchem.2014.09.022
Keywords
  • Methane
  • Ch-Activation
  • Palladium
  • Nhc
  • Catalysis

Abstract

Abstract A dimeric methyl palladium(II) biscarbene complex with a bridging μ-chloro ligand was prepared by transmetalation from 1,1′-dimethyl-3,3′-methylenediimidazolium dichloride, silver(I) oxide and chloridomethyl(cycloctadiene)palladium(II). The complex was fully characterized and shows good activity in the CH-activation of methane. The solid state structure confirms a symmetrical dimeric structure with a μ-coordinated chlorido ligand.

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