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catena-Poly[[[dichloridozinc(II)]-μ-1,4-bis­(1H-benzimidazol-2-yl-κN 3)butane] 1,4-bis­(1H-benzimidazol-2-yl)butane solvate]

Authors
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
1
Identifiers
DOI: 10.1107/s1600536809052635
Keywords
  • Metal-Organic Papers

Abstract

In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl2(C18H18N4)]·C18H18N4}n, the tetrahedrally coordinated ZnII ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but inter­acts with the chain through N—H⋯N and N—H⋯Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is disordered over three positions in a 0.511 (4):0.289 (5):0.200 (5) ratio.

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