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Reference compounds for14N nuclear magnetic resonance; the relative chemical shifts of aqueous nitrate ion and nitromethane

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
31
Issue
11
Identifiers
DOI: 10.1016/0584-8539(75)80111-5
Disciplines
  • Chemistry

Abstract

Abstract The 14N chemical shifts of aqueous nitrate ion and nitromethane are separated by at least 3 ppm. The use of NO − 3(aq) and CH 3NO 2 as internal standards in a unified scale for 14N chemical shifts must, therefore, be reconsidered.

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