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Catalysis of the Epoxidation of Olefins

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
32
Issue
27
Identifiers
DOI: 10.1016/s0040-4039(00)79712-7
Keywords
  • Mcpba Substitute Vanadium Oxide T-Butythydroperoxide - Selectivity

Abstract

Abstract By analogy between the oxo forms of vanadium (V) and iron (IV), the latter being the active species in oxidations by cytochrome P-450, the system constituted by vanadium oxide (catalyst) and t.-butylhydroperoxide (oxidant) gives good results in the conversation of olefins to the corresding epoxides.

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