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Bis[2-(1-imino­eth­yl)phenolato-κ2 N,O]nickel(II)

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
68
Issue
1
Identifiers
DOI: 10.1107/s1600536811051476
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

There are one and a half independent mol­ecules in the asymmetric unit of the title compound, [Ni(C8H8NO)2], one of which is situated on an inversion center. In both mol­ecules, the NiII ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter­molecular N—H⋯O hydrogen bonds link three mol­ecules into centrosymmetric trimer. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds and voids of 37 Å3.

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