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Chirality delivery through multiple and helical H-bonding from chiral coordination complex to its supramolecular architecture

Authors
Journal
Inorganic Chemistry Communications
1387-7003
Publisher
Elsevier
Volume
34
Identifiers
DOI: 10.1016/j.inoche.2013.04.038
Keywords
  • Chirality Delivery
  • Circular Dichroism
  • Nucleotide Complex
  • Supramolecular Architecture

Abstract

Abstract The path of the chirality delivery in the crystalline and chiral nucleotide–Co(II) complex, [Co(GMP)(H2O)5]·3H2O (GMP=guanosine-5′-monophosphate), has been studied based on X-ray single crystal diffraction analysis, liquid- and solid-state circular dichroism (CD) spectroscopy. The multiple and helical H-bonding is a distinctive way of chirality delivery from the discrete molecules to three-dimensional supramolecular architecture.

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