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The uv photolysis of chlorine azide

Authors
Journal
Journal of Photochemistry
0047-2670
Publisher
Elsevier
Publication Date
Volume
18
Issue
2
Identifiers
DOI: 10.1016/0047-2670(82)80015-4

Abstract

Abstract The photolysis of ClN 3 at 272 and 300 nm results in prompt emission between 600 and 900 nm from two different species which most probably are different states (either electronic or vibrational) of ClN. One state, at present still unidentified, has a radiative lifetime of 26 ± 5 μs and is quenched by Cl 2 with a rate constant of (7.5 ± 2) × 10 −12 cm 3 molecule −1 S −1. The other state, tentatively identified as the b 1Σ + state, has a radiative lifetime of 0.25 ± 0.05 ms and is quenched by Cl 2 with a rate constant of (1.5 ± 0.5) × 10 −13 cm 3 molecule −1 s −1.

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